There could be different reasons:
Make sure the booking window start and end time in your setting is set correctly.
To do that,
For example, if you set the "Booking window start time" to be 1 hour, then your clients will be able to schedule events with you 1 hour from now.
If you set the "Booking window end time" to be 30 days, then the last available time slot your clients will be able to schedule events with you is 30 days from now.
Make sure your regular hours are set correctly.
For example, if you want make your schedule available during the weekend, make sure Saturday and Sunday are selected.